Evolution with hole doping of the electronic excitation spectrum in the cuprate superconductors

The recent scanning tunnelling results of Alldredge and co-workers on Bi-2212 and of Hanaguri and co-workers on Na-CCOC (Ca(2-x)Na(x)CuO(2)Cl(2)) are examined from the perspective of the Bardeen-Cooper-Schrieffer (BCS)/Bose-Einstein condensation boson-fermion resonant crossover model for the mixed-valence high temperature superconductor (HTSC) cuprates. The model specifies the two energy scales controlling the development of HTSC behaviour and the dichotomy often now alluded to between nodal and antinodal phenomena in the HTSC cuprates. An indication is extracted from the data as to how the choice of the particular HTSC system sees these two basic energy scales ([Formula: see text], the local pair binding energy, and Δ(sc), the nodal BCS-like gap parameter) evolve with doping and change in the degree of metallization of the structurally and electronically perturbed mixed-valent environment.