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Published on: June 18, 2013
A Template-Free Method toward Urchin-Like Polyaniline Microspheres
Junsheng Wang1, Jixiao Wang, Zhi Wang
1State Key Laboratory of Chemical Engineering, Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China.
Abstract:
Urchin-like PANI microspheres with an average diameter of 5-10 µm have been successfully prepared. Their surfaces consist of highly oriented nanofibers of ≈30 nm diameter and 1 µm length. The solvent composition plays an important role in the formation process of urchin-like PANI microspheres. The structure of the products has been characterized by FT-IR, UV-vis, and XRD. To investigate the self-assembly of urchin-like PANI microspheres, the effect of polymerization time on the morphology of the products has been studied. The morphological evolution process indicates that the urchin-like microspheres originate from the self-assembly of nanoplates, which then grow into urchin-like microstructures with nanofibers on the surface.

