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Shear banding in thixotropic and normal emulsions
José Paredes1, Noushine Shahidzadeh-Bonn, Daniel Bonn
1Van der Waals-Zeeman Institute, University of Amsterdam, Amsterdam, The Netherlands.
Yield stress materials often flow inhomogeneously. This study shows shear banding in emulsions, particularly in thixotropic yield stress materials, due to a critical shear rate.
Area of Science:
- Rheology
- Fluid Dynamics
- Materials Science
Background:
- Yield stress materials transition from solid-like to liquid-like states when stress exceeds a critical threshold.
- Heterogeneous stress in materials leads to non-uniform flow behavior.
- Emulsion flow in cone-plate geometry typically represents a homogeneous stress scenario for Newtonian fluids.
Purpose of the Study:
- To investigate shear banding phenomena in emulsion flows within a cone-plate geometry.
- To differentiate between shear banding mechanisms, including wall slip and critical shear rate.
- To identify the specific conditions under which shear banding occurs in yield stress materials.
Main Methods:
- Utilizing a rheometer to control and measure material flow properties.
- Employing confocal laser scanning microscopy to obtain detailed velocity profiles.
- Analyzing emulsion flow behavior in a cone-plate rheometer.
Main Results:
- Shear banding was observed in emulsion flows, deviating from homogeneous flow expected for Newtonian fluids.
- Two distinct causes for shear banding were identified: wall slip and the existence of a critical shear rate.
- The study confirmed that shear banding related to a critical shear rate is exclusive to thixotropic yield stress materials.
Conclusions:
- Shear banding in emulsions is not solely dependent on heterogeneous stress but can arise from material-specific properties.
- Thixotropic yield stress materials exhibit a distinct shear banding mechanism linked to a critical shear rate.
- The combination of rheometry and advanced microscopy provides critical insights into complex fluid flow behaviors.
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