Applications of metal surfaces nanostructured by ion beam sputtering

We review results relative to the formation of regular nanoscale patterns on metal substrates exposed to defocused ion beam irradiation. Particular emphasis is placed on work which demonstrates the possibility of controllably modifying chemico-physical properties of the material by tailoring the nanoscale morphology during IBS patterning. Starting from the well-established results found on single-crystal model systems, we show how the controlled modification of the atomic step termination can deeply affect chemical reactivity or magnetic anisotropy. We then look in greater detail at the more recent attempts focused on the extension of IBS patterning on supported polycrystalline metal films, a promising class of systems in view of potential applications. A modification of the functional properties of metal films can also be obtained by forcing a shape anisotropy of the nanostructures. The modification of the optical response of polycrystalline metal nanowires supported on anisotropic templates produced by IBS provides a clear example of this.