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Updated: May 31, 2026

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Modeling optical properties of particles with small-scale surface roughness: combination of group theory with a
1Swedish Meteorological and Hydrological Institute (SMHI), Research Department, Norrköping, Sweden. michael.kahnert@smhi.se
Abstract:
A T-matrix method for scattering by particles with small-scale surface roughness is presented. The method combines group theory with a perturbation expansion approach. Group theory is found to reduce CPU-time by 4-6 orders of magnitude. The perturbation expansion extends the range of size parameters by a factor of 5 compared to non-perturbative methods. An application to optically hard particles shows that small-scale surface roughness changes scattering in side- and backscattering directions, and it impacts the single-scattering albedo. This can have important implications for interpreting remote sensing observations, and for the climate impact of mineral aerosols.
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