Structural reordering in monolayers of gold nanoparticles during transfer from water surface to solid substrate

Structural reordering in monolayers of gold nanoparticles during transfer from water surface to solid substrate has been studied by synchrotron x-ray scattering techniques. Grazing incidence diffraction (GID) and grazing incidence x-ray off-specular scattering (GIXOS) measurements were performed as a function of time to track the in-plane and out-of-plane structural reordering in the transferred monolayers. GID measurements show shift in the in-plane particle-particle correlation peak toward the lower in-plane momentum transfer value, signifying possible expansion of triangular lattice formed on the water surface. However, GIXOS data and supportive microscopy measurements clearly show compactification in the in-plane structure and associated out-of-plane movements. A model that assumes the possibility of a two-dimensional short-range structural reordering from triangular to square-like lattice as a function of time could explain all the data. The observed change in the electron densities of the nanoparticles before and after the structural reordering matches well with the expected change in the calculated electron densities of the nanoparticles arranged in triangular (pretransition) and square-like (post-transition) symmetry.