Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Olefin Metathesis Polymerization: Overview01:13

Olefin Metathesis Polymerization: Overview

Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
Free-Radical Chain Reaction and Polymerization of Alkenes02:35

Free-Radical Chain Reaction and Polymerization of Alkenes

The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a repeating unit, while the terminal groups are considered insignificant. The average degree of polymerization represents the number of repeating units in the polymer molecule and is denoted by the subscript n.
Types of Step-Growth Polymers: Polyesters01:20

Types of Step-Growth Polymers: Polyesters

The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the polymer...
Polymer Classification: Architecture01:14

Polymer Classification: Architecture

Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Anionic Chain-Growth Polymerization: Overview01:20

Anionic Chain-Growth Polymerization: Overview

The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Thiol-Michael Functionalized Polypyrrole Nanoparticles with Intrinsic Fluorescence and Electroactivity.

ACS applied nano materials·2026
Same author

Through-space donor-acceptor homoconjugation strategies for emissive radical species.

Chemical science·2026
Same author

Ultrasensitive Hydrogen Detection via Layered n-Type Polymer Chemiresistors.

Nano letters·2026
Same author

Photoactive PFA Coating through Fluorophilic Interactions for Continuous Flow Photochemistry.

JACS Au·2025
Same author

Stable Helical Assembly of Propellane-Based Polymers and Nanotube Composites.

ACS applied materials & interfaces·2025
Same author

Hexabenzocoronene-Benzimidazole Hybrid Architectures and Faraday Rotation of the First Hexabenzocoronene-Phthalocyanine.

Angewandte Chemie (International ed. in English)·2025
Same journal

Customizing Ionic Micelles by Dynamic Coassembly of Sequence-Defined Peptoid Block Copolymers.

Macromolecules·2026
Same journal

Investigating Polyethylene Solubility for Solvent-Based Recycling: Experiments and SAFT‑γ Mie Predictions.

Macromolecules·2026
Same journal

Molecular Dynamics Simulations of the Structural and Thermodynamic Properties of Poly(<i>l</i>‑lactic acid) in the Presence of Water.

Macromolecules·2026
Same journal

From Solvent-Mediated Micellization to Packing in a Face-Centered Cubic Structure of Poloxamers.

Macromolecules·2026
Same journal

Nonlocal Effect of Percolated Particle Networks on Viscoelasticity of Polymer-Filler Nanocomposites: A Mesoscale Simulation Study.

Macromolecules·2026
Same journal

Helicity of a confined bottlebrush ring polymer.

Macromolecules·2026
See all related articles

Related Experiment Video

Updated: May 31, 2026

Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties
10:16

Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties

Published on: January 8, 2016

Thermally-Polymerized Rylene Nanoparticles.

Trisha L Andrew1, Timothy M Swager

  • 1Massachusetts Institute of Technology, Department of Chemistry, 77 Massachusetts Avenue, Cambridge, MA 02139.

Macromolecules
|July 7, 2011
PubMed
Summary
This summary is machine-generated.

Researchers created water-soluble dye nanoparticles using phenyl trifluorovinylether (TFVE) functionalized rylene dyes. These shape-persistent nanoparticles maintain their optical properties and offer tunable colors from yellow to deep red.

More Related Videos

Evaluation of Polymeric Gene Delivery Nanoparticles by Nanoparticle Tracking Analysis and High-throughput Flow Cytometry
08:51

Evaluation of Polymeric Gene Delivery Nanoparticles by Nanoparticle Tracking Analysis and High-throughput Flow Cytometry

Published on: March 1, 2013

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
09:02

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

Published on: July 9, 2015

Related Experiment Videos

Last Updated: May 31, 2026

Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties
10:16

Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties

Published on: January 8, 2016

Evaluation of Polymeric Gene Delivery Nanoparticles by Nanoparticle Tracking Analysis and High-throughput Flow Cytometry
08:51

Evaluation of Polymeric Gene Delivery Nanoparticles by Nanoparticle Tracking Analysis and High-throughput Flow Cytometry

Published on: March 1, 2013

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
09:02

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

Published on: July 9, 2015

Area of Science:

  • Organic Chemistry
  • Materials Science
  • Nanotechnology

Background:

  • Rylene dyes are known for their optical properties.
  • Developing stable, water-soluble nanoparticles with tunable colors is challenging.

Purpose of the Study:

  • To synthesize novel rylene dye derivatives functionalized with phenyl trifluorovinylether (TFVE) moieties.
  • To create shape-persistent, water-soluble chromophore nanoparticles via thermal emulsion polymerization.
  • To investigate the photophysical properties and color tunability of these nanoparticles.

Main Methods:

  • Synthesis of perylene and terrylene diimide derivatives with two or four phenyl TFVE groups.
  • Thermal emulsion polymerization in tetraglyme.
  • Dynamic light scattering for particle size analysis.
  • Photophysical characterization of monomers and nanoparticles.

Main Results:

  • Obtained nanoparticles ranging from 70-100 nm in size, dependent on monomer concentration.
  • Preserved individual monomer photophysical properties within the nanoemulsions.
  • Achieved tunable emission colors from yellow to deep red.
  • Demonstrated shape persistence upon dissolution in water.
  • Observed moderate to high fluorescence quantum yield in aqueous suspensions.

Conclusions:

  • Successfully developed shape-persistent, water-soluble rylene dye nanoparticles.
  • Demonstrated the potential for color tuning through TFVE functionalization.
  • Highlighted the utility of these nanoparticles for applications requiring stable, fluorescent aqueous solutions.