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Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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Oriented synthesis of one-dimensional polypyrrole molecule chains in a metal-organic framework
Qiang-Xin Wang1, Chun-Yang Zhang
1Institute of Biomedical Engineering and Health Technology, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China.
Macromolecular Rapid Communications
|July 7, 2011
Abstract:
We report for the first time the preparation of single polypyrrole (PPy) molecule chains using a "metal-organic framework" with 1 nm channels as a template. The obtained one-dimensional (1-D) PPy has highly structure order and excellent conductivity, which has improved by as much as five orders of magnitude in comparison with that of 2-D PPy.
