Related Experiment Video
Updated: May 31, 2026

Angle-resolved Photoemission Spectroscopy At Ultra-low Temperatures
Published on: October 9, 2012
Valence band circular dichroism in non-magnetic Ag/Ru(0001) at normal emission
Arantzazu Mascaraque1, T Onur Menteş, Kevin F McCarty
1Departamento Física de Materiales, Universidad Complutense de Madrid, Madrid 28040, Spain.
Abstract:
For the non-magnetic system of Ag films on Ru(0001), we have measured the circular dichroism of photoelectrons emitted along the surface normal, the geometry typically used in photoemission electron microscopy. Photoemission spectra were acquired from micrometer-sized regions having uniformly thick Ag films on a single, atomically flat Ru terrace. For a single Ag layer, we find a circular dichroism that exceeds 6% at the d-derived band region around 4.5 eV binding energy. The dichroism decreases as the Ag film thickness increases to three atomic layers. We discuss the origin of the circular dichroism in terms of the symmetry lowering that can occur even in normal emission.
More Related Videos
10:22In Situ SIMS and IR Spectroscopy of Well-defined Surfaces Prepared by Soft Landing of Mass-selected Ions
Published on: June 16, 2014
09:06Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
Published on: March 24, 2019
Related Concept Videos
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Valence Bond Theory
UV–Vis Spectroscopy: Molecular Electronic Transitions
IR Absorption Frequency: Delocalization
In IR spectroscopy,...
Molecular Spectroscopy: Absorption and Emission
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...