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Updated: May 31, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
10:39

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction

Published on: August 23, 2018

High-turnover supramolecular catalysis by a protected ruthenium(II) complex in aqueous solution

Casey J Brown1, Gregory M Miller, Miles W Johnson

  • 1Chemical Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720, USA.

Journal of the American Chemical Society
|July 9, 2011
PubMed
Summary

A novel supramolecular catalyst using a ruthenium(II) complex within a water-soluble assembly enables high-turnover allyl alcohol isomerization. This host-guest system protects the catalyst while maintaining high activity, achieving over 1000 turnovers.

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