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Synthesis and Performance Evaluations of ZnCoS/ZnCdS with Twin Crystal Structure for Multifunctional Redox Photocatalysis in Energy Applications

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Published on: July 25, 2025

Cu(2)ZnSiS(4).

Kimberly A Rosmus¹, Jennifer A Aitken

¹Department of Chemistry and Biochemistry, Duquesne University, 600 Forbes Avenue, Pittsburgh, PA 15282, USA.

Acta Crystallographica. Section E, Structure Reports Online

|July 15, 2011

Summary

This summary is machine-generated.

Dicopper(I) zinc silicon tetrasulfide (Cu(2)ZnSiS(4)) single crystals were synthesized. The material crystallizes in the wurtz-stannite structure, featuring a unique three-dimensional honeycomb arrangement of atoms.

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Synthesis of Hierarchical ZnO/CdSSe Heterostructure Nanotrees

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Published on: November 29, 2016

Area of Science:

Solid-state chemistry
Crystallography
Materials science

Background:

The wurtz-stannite structure is a notable crystal structure with potential applications in materials science.
Understanding the synthesis and structural properties of related compounds is crucial for discovering new materials.

Purpose of the Study:

To synthesize single crystals of dicopper(I) zinc silicon tetrasulfide (Cu(2)ZnSiS(4)).
To determine the crystal structure of the synthesized Cu(2)ZnSiS(4).
To investigate the atomic arrangement and coordination within the Cu(2)ZnSiS(4) structure.

Main Methods:

High-temperature solid-state synthesis was employed for crystal preparation.
X-ray crystallography techniques were used to determine the crystal structure.
Analysis of atomic coordination and arrangement was performed.

Main Results:

Single crystals of Cu(2)ZnSiS(4) were successfully prepared.
The compound was identified to possess the wurtz-stannite structure type.
A three-dimensional honeycomb structure was observed, with tetrahedral coordination around each sulfur anion by two Cu, one Zn, and one Si cation.

Conclusions:

Cu(2)ZnSiS(4) crystallizes in the wurtz-stannite structure.
The synthesis and structural characterization provide foundational data for further research into this material.
The observed atomic arrangement offers insights into structure-property relationships in related compounds.