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Updated: May 31, 2026

Discovery and Synthesis Optimization of Isoreticular Al(III) Phosphonate-Based Metal-Organic Framework Compounds Using High-Throughput Methods
Published on: October 6, 2023
catena-Poly[[[diaqua-(2-fluoro-benzoato-κO,O')strontium]-μ(3)-2-fluoro-benzoato-κO:O,O':O',F] monohydrate]
1College of Materials Science and Chemical Engineering, Jinhua College of Profession and Technology, Jinhua, Zhejiang 321017, People's Republic of China.
Abstract:
In the title compound, {[Sr(C(7)H(4)FO(2))(2)(H(2)O)(2)]·H(2)O}(n), the Sr(II) atom is coordinated by six O atoms and one F atom from four 2-fluoro-benzoate ligands and two water mol-ecules, resulting in an irregular SrFO(8) coordination environment. The μ(3)-2-fluoro-benzoate ligand bridges three symmetry-related Sr(II) atoms, giving rise to a chain structure extending along [010]. The polymeric chains are connected via O-H⋯O hydrogen bonds into a two-dimensional supra-molecular structure parallel to (100).
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