Related Experiment Video
Updated: May 31, 2026

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Bis(3,5-dimethyl-1H-pyrazole-κN)silver(I) hexa-fluorido-anti-monate
Devyn Crawford1, Anthony K Hofer, Kate L Edler
1CB 4160, Department of Chemistry, Illinois State University, Normal, IL 61790, USA.
Abstract:
The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N-Ag-N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethyl-pyrazole H atoms and two F atoms of one hexa-fluorido-anti-monate anion. Three relatively short Ag⋯F contacts [2.869 (6), 2.920 (7), and 3.094 (7) Å] exist between the cation and three different SbF(6) (-) anions. The crystal used for data collection was found to be twinned by non-merohedry, with the two components being related by a 180° rotation around the real or reciprocal a axis. Integration resulted in 11.2% of the total peaks being assigned to component 1, 11.2% to component 2, and 77.6% to both components.
More Related Videos
10:29Multi-photon Intracellular Sodium Imaging Combined with UV-mediated Focal Uncaging of Glutamate in CA1 Pyramidal Neurons
Published on: October 8, 2014
19:58Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017