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N-Cyclo-hexyl-4-meth-oxy-benzene-sulfonamide
Summary
This study details the molecular structure of a novel compound, C(13)H(19)NO(3)S, revealing a distorted tetrahedral sulfur atom and a chair conformation cyclohexane ring. Molecules form zigzag chains via intermolecular hydrogen bonds in the crystal structure.
Area of Science:
- Crystallography
- Molecular Chemistry
Background:
- Understanding the three-dimensional arrangement of atoms in molecules is crucial for predicting chemical properties and reactivity.
- Crystal structure analysis provides detailed insights into molecular geometry and intermolecular interactions.
Purpose of the Study:
- To elucidate the detailed crystal structure and molecular geometry of the compound C(13)H(19)NO(3)S.
- To investigate the intermolecular interactions governing the crystal packing.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond angles, bond lengths, and intermolecular contacts was performed.
Main Results:
- The sulfur atom exhibits a distorted tetrahedral geometry with a specific O-S-O bond angle of 120.39(18)°.
- The cyclohexane ring adopts a chair conformation.
- Intermolecular N-H⋯O hydrogen bonds link molecules into zigzag chains along the c-axis.
Conclusions:
- The study provides a precise description of the molecular structure and crystal packing of C(13)H(19)NO(3)S.
- The identified hydrogen bonding network is a key feature influencing the solid-state architecture.
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