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Updated: May 31, 2026
11:04
Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
Published on: June 13, 2022
(E)-N'-(2-Bromo-benzyl-idene)-2-fluoro-benzohydrazide
Summary
This study details the crystal structure of a novel brominated fluorinated organic compound. Molecules form chains via intermolecular hydrogen bonds, revealing its solid-state arrangement.
Area of Science:
- Organic Chemistry
- Crystallography
- Materials Science
Background:
- Understanding the solid-state structure of organic compounds is crucial for predicting their physical and chemical properties.
- The specific arrangement of molecules in crystals influences intermolecular interactions and material behavior.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(14)H(10)BrFN(2)O.
- To characterize the molecular geometry and intermolecular interactions in the solid state.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the three-dimensional structure.
- Analysis of bond lengths, bond angles, and dihedral angles provided geometric information.
- Identification of intermolecular interactions, such as hydrogen bonds, was performed.
Main Results:
- The compound C(14)H(10)BrFN(2)O exhibits an E geometry around the C=N bond.
- A significant dihedral angle of 81.5(6)° was observed between the two benzene ring planes.
- Intermolecular N-H⋯O hydrogen bonds link molecules into chains along the b-axis.
Conclusions:
- The crystal structure reveals a specific spatial arrangement and intermolecular bonding pattern.
- The observed E geometry and dihedral angle are key features of this molecule's solid-state conformation.
- The formation of hydrogen-bonded chains suggests potential applications in supramolecular chemistry or crystal engineering.
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