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Updated: May 31, 2026
06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(E)-1-(4-Meth-oxy-anthracen-1-yl)-2-phenyl-diazene
Summary
This study details the E-conformation of a novel C(21)H(16)N(2)O compound. Its crystal structure reveals a near-planar arrangement stabilized by C-H⋯π and π-π interactions, forming 2D networks.
Area of Science:
- Crystallography
- Organic Chemistry
- Materials Science
Background:
- Understanding molecular conformation and crystal packing is crucial for designing new materials.
- Diazene compounds exhibit diverse electronic and structural properties.
- Anthracene derivatives are widely studied for their photophysical and structural characteristics.
Purpose of the Study:
- To elucidate the crystal structure and conformation of the title compound, C(21)H(16)N(2)O.
- To investigate the intermolecular interactions stabilizing the crystal lattice.
- To characterize the three-dimensional network formed by the molecules in the solid state.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, bond angles, and torsion angles provided conformational information.
- Intermolecular interactions, including C-H⋯π and π-π stacking, were identified and quantified.
Main Results:
- The compound adopts an E-conformation around the diazene N=N bond.
- The molecule is nearly planar, with the phenyl ring tilted at 6.43° relative to the anthracene moiety.
- Crystal structure is stabilized by C-H⋯π and weak π-π interactions, forming 2D networks parallel to the (110) plane.
Conclusions:
- The determined crystal structure provides fundamental insights into the solid-state behavior of this diazene derivative.
- The observed planar structure and stabilizing interactions are key factors for potential applications in materials science.
- Further studies can explore the electronic and optical properties stemming from this specific molecular arrangement.
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