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Updated: May 31, 2026
08:46
Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Diphenyl (o-tolyl-amido)-phospho-nate
Summary
This study characterizes a novel compound, C(19)H(18)NO(3)P, revealing two independent molecules within its crystal structure. Intermolecular hydrogen bonds link these molecules into centrosymmetric dimers.
Area of Science:
- Crystallography
- Chemical Physics
Background:
- Understanding molecular interactions and crystal packing is crucial in materials science.
- The study of organophosphorus compounds contributes to diverse chemical applications.
Purpose of the Study:
- To elucidate the crystal structure and intermolecular interactions of the title compound, C(19)H(18)NO(3)P.
- To analyze the coordination environment around the phosphorus atoms and the hydrogen bonding network.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, angles, and intermolecular contacts was performed.
Main Results:
- The asymmetric unit contains two independent molecules of C(19)H(18)NO(3)P.
- Phosphorus atoms exhibit slightly distorted tetrahedral coordination geometries.
- Two independent centrosymmetric dimers are formed via intermolecular N-H⋯O(P) hydrogen bonds.
Conclusions:
- The crystal structure of C(19)H(18)NO(3)P is characterized by discrete molecular units and specific hydrogen-bonding motifs.
- The observed hydrogen bonding influences the self-assembly of molecules in the solid state.
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