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Updated: May 31, 2026
19:58
Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
2-Bromo-N-(dibenzyl-carbamothioyl)benzamide
Summary
The crystal structure of a novel organic compound reveals a specific molecular conformation. This structure is stabilized by intermolecular hydrogen bonds, forming a one-dimensional chain.
Area of Science:
- Crystallography
- Organic Chemistry
- Molecular Structure
Background:
- Understanding molecular conformation is crucial in chemistry.
- Crystal structure analysis provides insights into intermolecular interactions.
Purpose of the Study:
- To determine the crystal structure of the title compound C(22)H(19)BrN(2)OS.
- To investigate the molecular conformation and intermolecular interactions.
Main Methods:
- Single-crystal X-ray diffraction was employed.
- Analysis of the crystal packing and hydrogen bonding network.
Main Results:
- The 2-bromo-benzoyl group adopts an E conformation.
- Intermolecular N-H⋯O hydrogen bonds stabilize the molecule.
- A one-dimensional chain structure along the b axis was observed.
Conclusions:
- The study elucidates the solid-state structure of the compound.
- Hydrogen bonding plays a key role in the observed crystal packing.
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