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The Effect of Ultraviolet Radiation on the Chemical Bath Deposition of Bis(thiourea) Cadmium Chloride Crystals and the Subsequent CdS Obtention
Published on: August 30, 2018
Bis(1,10-phenanthroline-κN,N')bis-(thio-cyanato-κN)cadmium
Daniel Vallejo1, Garikoitz Beobide, Oscar Castillo
1Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, E-48080 Bilbao, Spain.
Abstract:
The title compound, [Cd(NCS)(2)(C(12)H(8)N(2))(2)], has been obtained from the decomposition reaction of dithio-oxamide in a dimethyl-formamide solution containing 1,10-phenanthroline (phen) and Cd(NO(3))(2)·4H(2)O. Its crystal structure is formed by monuclear Cd(II) entities in which the metal atom is sited on a twofold rotation axis. The Cd(II) atom is six-coordinated in the form of a distorted octa-hedron by two chelating phenanthroline mol-ecules and two thio-cyanate anions coordinated through their N atoms. In the crystal, C-H⋯N hydrogen bonds are established between the phenanthroline and thio-cyanate ligands of neighbouring complexes.
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