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Updated: May 31, 2026
09:35
Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
catena-Poly[[cobalt(II)-μ-aqua-di-μ-butano-ato-κO:O';κO:O] 0.7-hydrate]
Summary
This study describes a novel coordination polymer containing cobalt. The structure features polymeric chains linked by hydrogen bonds, forming sheets with disordered water molecules and disordered butanoate anions.
Area of Science:
- Coordination Chemistry
- Materials Science
- Crystallography
Background:
- Coordination polymers are materials with diverse applications.
- Understanding the structural features of cobalt-based coordination polymers is crucial for developing new functional materials.
Purpose of the Study:
- To synthesize and characterize a novel coordination polymer of cobalt(II).
- To elucidate the crystal structure and supramolecular assembly of the {[Co(C(3)H(7)COO)(2)(H(2)O)]·0.7H(2)O}(n) complex.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the crystal structure.
- Analysis of coordination environment and hydrogen bonding interactions.
Main Results:
- The cobalt(II) cation exhibits a severely distorted octahedral coordination geometry.
- Polymeric chains along the [010] direction are formed by bridging butanoate anions and water molecules.
- These chains assemble into sheets parallel to (001) via hydrogen bonds involving disordered water molecules.
- Disorder was observed in water molecules and butanoate anion aliphatic chains.
Conclusions:
- The study successfully characterized a new cobalt coordination polymer with a layered structure.
- The observed structural features, including disorder, provide insights into the self-assembly of such materials.
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