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Updated: May 31, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
08:46

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)

Published on: November 22, 2016

rac-2,2'-Bipiperidine-1,1'-diium dibromide.

Marju Laars1, Kerti Ausmees, Marina Kudrjashova

  • 1Tallinn University of Technology, Department of Chemistry, Akadeemia tee 15, 12618 Tallinn, Estonia.

Acta Crystallographica. Section E, Structure Reports Online
|July 15, 2011
PubMed
Summary

The crystal structure of a bipiperidinium compound, a precursor for organocatalysts, reveals a chair conformation and N-H⋯Br hydrogen bonds forming layered structures. This finding aids in understanding organocatalyst synthesis.

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