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Updated: May 31, 2026
08:43
Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
4-Meth-oxy-3-(4-nitro-benz-yloxy)benzaldehyde.
Zhong-Yu Duan1, Guo-Li Ma, Li-Ping Yang
1College of Chemical Engineering, Hebei University of Technology, Tianjin 300130, People's Republic of China.
Summary
This study details the crystal structure of a novel organic compound, C(15)H(13)NO(5). Molecular analysis reveals specific benzene ring orientation and intermolecular interactions influencing crystal packing.
Area of Science:
- Crystallography
- Organic Chemistry
- Solid-State Chemistry
Background:
- Understanding molecular interactions is crucial for predicting material properties.
- Crystal structure analysis provides fundamental insights into intermolecular forces.
Purpose of the Study:
- To elucidate the crystal structure of the compound C(15)H(13)NO(5).
- To investigate the nature of intermolecular interactions governing crystal packing.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, angles, and non-covalent interactions was performed.
Main Results:
- The crystal structure of C(15)H(13)NO(5) was successfully determined.
- A small dihedral angle of 3.98(7)° was observed between the two benzene rings.
- Crystal packing is characterized by centrosymmetric tetramers formed via C-H⋯O interactions.
Conclusions:
- The study provides a detailed structural characterization of C(15)H(13)NO(5).
- Non-classical C-H⋯O interactions play a significant role in stabilizing the crystal lattice.
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