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Updated: May 31, 2026
08:43
Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
2-(4-Bromo-phen-yl)-2-oxoethyl 4-meth-oxy-benzoate
Summary
This study details the crystal structure of a brominated organic compound. Molecules form chains through hydrogen bonds, with benzene rings nearly perpendicular.
Area of Science:
- Crystallography
- Organic Chemistry
- Supramolecular Chemistry
Background:
- Understanding molecular interactions is key in crystal engineering.
- The specific arrangement of organic molecules influences material properties.
Purpose of the Study:
- To elucidate the crystal structure of the title compound C(16)H(13)BrO(4).
- To investigate intermolecular interactions governing crystal packing.
Main Methods:
- Single-crystal X-ray diffraction was employed.
- Analysis of hydrogen bonds and C-H⋯π interactions was performed.
Main Results:
- The crystal structure reveals benzene rings with a dihedral angle of 84.07(8)°.
- Intermolecular C-H⋯O hydrogen bonds link molecules into chains along the a axis.
- A C-H⋯π interaction was identified within the crystal lattice.
Conclusions:
- The crystal packing is dictated by a combination of hydrogen bonding and C-H⋯π interactions.
- The near-perpendicular orientation of benzene rings influences the overall molecular conformation and packing.
- This structural information contributes to the understanding of organic crystal formation and design.
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