New deep blue emitting materials based on indenopyrazine core with high thermal stability
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Updated: May 30, 2026

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Chang-Hun Seok1, Young-Il Park, Soo-Kang Kim
1Department of Chemistry, The Catholic University of Korea, Bucheon 420-743, Republic of Korea.
Abstract:
New deep blue emitting materials 2,8-bis(3,5-diphenylphenyl)-6,6,12,12-tetraethyl-6,12-dihydrodiindeno[1,2-b:1',2'-e]pyrazine (DPP-EPY) and 2,8-bis(3',5'-diphenylbiphenyl-4-yl)-6,6,12,12-tetraethyl-6,12-dihydrodiindeno[1,2-b:1',2'-e]pyrazine (DPBP-EPY) were synthesized through introduction of m-terphenyl or triphenylbenzene bulky side groups in a new indenopyrazine core. These materials all showed high thermal stability and highly reduced intermolecular interaction. DPP-EPY and DPBP-EPY showed PL maxima of 456 nm and 460 nm in deep blue region and narrow PL spectra with full-width at half-maximum (FWHM) of 46 nm and 52 nm, respectively. As a result of making non-doped OLED devices using these synthesized materials as emitting layers, DPP-EPY showed EL spectrum of 452 nm, very narrow FWHM of 46 nm, luminance efficiency of 1.04 cd/A with current density of 10 mA/cm2 and CIE coordinate of (0.161, 0.104), creating a deep blue OLED close to the National Television System Committee (NTSC) blue standard.
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