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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Published on: April 19, 2019

Interconversion study in 1,4-substituted six-membered cyclohexane-type rings. Structure and dynamics of

Alex D Bain1, Maximo Baron, Steven K Burger

  • 1Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Ontario L8S 4M1, Canada. bain@mcmaster.ca

The Journal of Physical Chemistry. A
|July 27, 2011
PubMed
Summary

The study investigates the dynamic interconversion between cyclohexane conformations in trans-1,4-dibromo-1,4-dicyanocyclohexane. Variable-temperature NMR and computational methods reveal the activation enthalpy for this dynamic process.

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