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Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds
Published on: October 15, 2019
PAs3S3 cage as a new building block in copper halide coordination polymers
Patrick Schwarz1, Joachim Wachter, Manfred Zabel
1Institut für Anorganische Chemie, Universität Regensburg, D-93040 Regensburg, Germany.
Inorganic Chemistry
|July 30, 2011
Summary
This study introduces new coordination compounds using the PAs(3)S(3) cage ligand with copper halides. These novel structures showcase the ligand
Area of Science:
- Inorganic Chemistry
- Coordination Chemistry
- Materials Science
Background:
- The PAs(3)S(3) cage is a novel ligand with potential applications in coordination chemistry.
- Understanding the coordination behavior of PAs(3)S(3) with transition metals is crucial for developing new materials.
Purpose of the Study:
- To synthesize and characterize new coordination compounds of the PAs(3)S(3) cage with copper.
- To investigate the coordination versatility and structural diversity of PAs(3)S(3) in copper complexes.
Main Methods:
- Interdiffusion techniques were used to synthesize the coordination compounds.
- Raman spectroscopy and single-crystal X-ray crystallography were employed for characterization.
Main Results:
- First examples of PAs(3)S(3) coordination chemistry with copper were obtained.
- Structures reveal diverse coordination modes of PAs(3)S(3), involving apical phosphorus and bridging sulfur atoms.
- Framework dimensionality is influenced by As···X interactions, leading to polycatenane and layered structures.
Conclusions:
- The PAs(3)S(3) ligand exhibits unexpected coordination versatility.
- The resulting coordination compounds display complex structural architectures, including polycatenanes and 2D layers.
- These findings open new avenues for designing novel inorganic materials with tailored properties.
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