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Updated: May 30, 2026
Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Functionalizing porous zirconium terephthalate UiO-66(Zr) for natural gas upgrading: a computational exploration
Qingyuan Yang1, Andrew D Wiersum, Philip L Llewellyn
1Department of chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Abstract:
The ligand functionalization effect on the CO(2)/CH(4) separation performance of the MOF type UiO-66(Zr) was explored computationally. The -SO(3)H and -CO(2)H functionalized forms show the highest selectivity, good working capacity and medium ranged CO(2) adsorption enthalpy that make these materials very promising for physisorption-based processes.
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