Pulsed jet discharge matrix isolation and computational study of bromine atom complexes: Br···BrXCH(2) (X = H, Cl,...

Halogen atoms are important reactive radicals in the atmosphere. In this work, pulsed jet discharge matrix isolation spectroscopy and computational methods were used to characterize prereactive complexes of halogen atoms with simple halons. Our experiments combined matrix isolation techniques with a pulsed DC discharge nozzle, where a dilute CH(2)XBr (X = H, Cl, Br)/rare gas sample was gently discharged and the products were deposited onto a cold KBr window. The Br···BrCH(2)X (X = H, Cl, Br) complexes were characterized by infrared and electronic spectroscopy, supported by ab initio and density functional theory (DFT) calculations, which shed light on the structure of, bonding in, and binding energy of the complexes. The correlation of charge-transfer energy with donor ionization potential (Mulliken correlation) was examined, and the charge-transfer photochemistry of the complexes was explored.