Spin glass behaviors compatible with a Zhang-Rice singlet within an effective model for cuprate superconductors

To address the incompatibility of Zhang-Rice singlet formation and the observed spin glass behavior, an effective model is proposed for the electronic behavior of cuprate materials. The model includes an antiferromagnetic interaction between the spin of the hole in a Zhang-Rice orbital and the spin of the hole on the corresponding copper site. While in the large interaction limit this recovers the t-J model, in the low energy limit the Zhang-Rice singlets are deformed. It is also shown that such deformation can induce random defect ferromagnetic (FM) bonds between adjacent local spins, an effect herein referred to as unusual double exchange, and then spin glass behavior shall result in the case of localized holes. A derivation of the model is also presented.