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Related Concept Videos

Colors and Magnetism03:02

Colors and Magnetism

Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Diamagnetism01:26

Diamagnetism

Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets.
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
Atomic Nuclei: Nuclear Magnetic Moment00:59

Atomic Nuclei: Nuclear Magnetic Moment

All atomic nuclei are positively charged. When they have a nonzero spin, they behave like rotating charges. As a consequence of their charge and spin, these nuclei generate a magnetic field (B). This, in turn, gives rise to a magnetic moment (μ), which is randomly oriented in the absence of an external magnetic field. When an external magnetic field (B0) is applied, the magnetic moment vectors can align with the field or against it in 2 + 1 orientations. A hydrogen nucleus, which is just a...
Atomic Nuclei: Nuclear Relaxation Processes01:23

Atomic Nuclei: Nuclear Relaxation Processes

In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis,  the precessing magnetic moments are randomly oriented around the z-axis. This...
Paramagnetism01:30

Paramagnetism

Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...

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Related Experiment Video

Updated: May 30, 2026

Measurement of Coherence Decay in GaMnAs Using Femtosecond Four-wave Mixing
15:58

Measurement of Coherence Decay in GaMnAs Using Femtosecond Four-wave Mixing

Published on: December 3, 2013

Magnetic short-range order in β-Mn(1-x)Co(x).

J R Stewart1, R Cywinski

  • 1ISIS, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot OX11 0QX, UK.

Journal of Physics. Condensed Matter : an Institute of Physics Journal
|August 6, 2011
PubMed
Summary
This summary is machine-generated.

Cobalt addition to beta-manganese metal creates a disordered magnetic structure. Both 8c and 12d lattice sites contribute to the magnetic ground state, challenging previous assumptions.

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Radio Frequency Magnetron Sputtering of GdBa2Cu3O7&#8722;&#948;/ La0.67Sr0.33MnO3 Quasi-bilayer Films on SrTiO3 (STO) Single-crystal Substrates
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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
08:55

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses

Published on: June 7, 2018

Area of Science:

  • Condensed matter physics
  • Materials science
  • Magnetism

Background:

  • Beta-manganese (β-Mn) is an elemental metal with a complex crystal structure.
  • Understanding the magnetic properties of β-Mn and its alloys is crucial for materials science applications.
  • Previous studies suggested that specific lattice sites in β-Mn were non-magnetic.

Purpose of the Study:

  • To investigate the magnetic ground state properties of β-Mn metal alloyed with Cobalt (Co).
  • To analyze the magnetic structure and Mn-Mn spin correlations in Co-doped β-Mn.
  • To determine the contribution of different lattice sites to the magnetic ground state.

Main Methods:

  • Neutron polarization analysis of the diffuse neutron scattering cross-section.
  • Reverse Monte Carlo (RMC) procedure for magnetic structure analysis.
  • Extraction and analysis of Mn-Mn spin correlations.

Main Results:

  • The addition of Co to β-Mn results in a static disordered magnetic structure.
  • Medium-range magnetic correlations are observed in the alloy.
  • Analysis revealed that both 8c and 12d lattice sites contribute to the magnetic ground state.
  • Contrary to prior beliefs, the 8c site is found to be magnetic.

Conclusions:

  • Cobalt alloying induces a complex, disordered magnetic state in β-Mn.
  • The magnetic ground state arises from contributions from both 8c and 12d lattice sites.
  • This finding revises the understanding of magnetism in the β-Mn structure.