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Published on: May 2, 2014
Preparation of porous chromium oxide nanotubes using carbon nanotubes as templates and their application as an
Guimin An1, Yang Zhang, Zhimin Liu
1Beijing National Laboratory for Molecular Science (BNLMS), Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Science, Beijing 100080, People's Republic of China.
Abstract:
Chromium oxide nanotubes were successfully prepared using multi-walled carbon nanotubes (MWCNTs) as a template via a supercritical fluid-mediated route. In this method, with chromium (III) nitrate nonahydrate as precursor, chromium oxide was first deposited on MWCNTs in supercritical ethanol in the presence of NH(4)HCO(3). The as-prepared chromium oxide/MWCNT nanocomposites were characterized by transmission electron microscopy, x-ray diffraction, infrared spectroscopy and thermogravimetric analysis. It was demonstrated that the MWCNTs were coated with a layer of amorphous Cr(2)O(3)·xH(2)O. The thickness of the Cr(2)O(3)·xH(2)O sheath on MWCNTs could be tuned by manipulating the ratio of precursor to MWCNTs. Calcining the composites at 550 °C, the MWCNTs were removed, producing polycrystalline α-Cr(2)O(3) nanotubes. The as-prepared α-Cr(2)O(3) sample was used as a sensor material to detect ethanol vapor, and it was demonstrated that the α-Cr(2)O(3) nanotubes exhibited good performance even at 400 °C.
