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Updated: May 30, 2026
Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Hierarchical self-assembly of polyhedral oligomeric silsesquioxane end-capped stimuli-responsive polymer: from single
Li Ma1, Haiping Geng, Jiangxuan Song
1State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Abstract:
Responsive polymeric micelles have been widely studied because of their potential use in nanocontainers and nanocarriers. In this study, polyhedral oligomeric silsesquioxane (POSS) end-capped poly[2-(dimethylamino)ethyl methacrylate] (POSS-PDMAEMA), a stimuli-responsive organic-inorganic hybrid polymer, was synthesized via atom transfer radical polymerization (ATRP) using POSS-Br as a macroinitiator. The self-assembly behaviors of POSS-PDMAEMA in aqueous solution were studied by fluorescence probe, transmission electron microscopy (TEM), dynamic light scattering (DLS), high-resolution transmission electron microscopy (HRTEM), and X-ray diffraction (XRD). The results revealed two self-assembly processes of POSS-PDMAEMA. First they self-assembled into a single micelle with the POSS molecules forming a crystal core and the PDMAEMA chains stretching as a corona. Then the single micelles, as building blocks, were able to reversibly form a hierarchical micelle-on-micelle structure (complex micelle) under external stimuli.
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