Superconductivity and disorder in PrOs(4)Sb(12)

The specific heat, and dc and ac magnetic susceptibility are reported for a large single crystal of PrOs(4)Sb(12) and, after grinding, its powder. The physical properties of the crystal are typical of the majority of reported PrOs(4)Sb(12) samples. The room temperature effective paramagnetic moment of the crystal was consistent with the Pr(3+) ionic configuration and full (or nearly full) occupancy of the Pr sublattice. The crystal showed two distinct anomalies in the specific heat and an overall discontinuity in C/T of approximately 1000 mJ K(-2) mol(-1). The upper transition (at T(c1)) was characteristically rounded. The anomaly at T(c2) was very sharp, consistent with a good quality for the crystal. We observed a shoulder in χ(') and two peaks in χ('') below T(c1). However, there were no signatures in χ(') of the lower temperature transition. Grinding to powder size smaller than 50 µm completely suppresses the upper superconducting transition in both the specific heat and magnetic susceptibility. It also strongly reduces ΔC/T(c) at T(c2). Stress annealing brings back some of this lost ΔC/T(c) but does not restore the upper temperature transition. Possible explanations of the existence of two superconducting specific heat anomalies for single crystals are discussed.