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Updated: May 30, 2026

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Published on: October 9, 2012
Spin-lozenge thermodynamics and magnetic excitations in Na(3)RuO(4)
J T Haraldsen1, M B Stone, M D Lumsden
1Department of Physics and Astronomy, University of Tennessee, Knoxville, TN 37996, USA. Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.
Abstract:
We report inelastic and elastic neutron scattering, magnetic susceptibility, and heat capacity measurements for polycrystalline sodium ruthenate (Na(3)RuO(4)). Previous work suggests that this material consists of isolated tetramers of S = 3/2 Ru(5+) ions in a so-called lozenge configuration. Comparisons of magnetic susceptibility and inelastic and elastic neutron scattering results with analytic calculations for several cluster models show that although there may be significant spin-spin correlations within the lozenge cluster, a simple isolated lozenge model is not appropriate for Na(3)RuO(4).
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