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Updated: May 30, 2026

Atomic Layer Deposition of Vanadium Dioxide and a Temperature-dependent Optical Model
Published on: May 23, 2018
Redetermination of μ-oxido-bis-[bis-(N,N-diethyl-hydroxyl-aminato)-oxido-vanadium(V)]
Heng-Qiang Zhang1, Zhong-Min Jin, Xin Fan
1Department of Chemistry, East China Normal University, Shanghai 200062, People's Republic of China.
Abstract:
In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980 ▶). Nouv. J. Chim.4, 235-237] of the title compound, [V(2)(C(4)H(10)NO)(4)O(3)], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordinates and displacement parameters. The two V(V) atoms are each surrounded by two deprotonated N,O-bidentate diethyl-hydroxy-laminate groups, and a terminal and a bridging oxide ligand, in a distorted octa-hedral coordination geometry. The crystal packing is accomplished by van der Waals inter-actions.
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