Related Experiment Video
Updated: May 30, 2026
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
6-Phenyl-6,7-dihydro-dibenzo[c,f][1,5]aza-bis-mocin-12(5H)-yl perchlorate
Abstract:
In the title compound, [Bi(C(20)H(17)N)(ClO(4))] or C(20)H(17)BiClNO(4), the Bi(III) ion assumes a distorted ψ trigonal-bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical positions. Weak inter-molecular C-H⋯O hydrogen bonding is present in the crystal structure.
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