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Updated: May 30, 2026
Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition
Published on: February 5, 2022
cis-Dichloridobis-(5,5'-dimethyl-2,2'-bipyridine)-manganese(II) 2.5-hydrate
Lívia Batista Lopes1, Charlane Cimini Corrêa, Renata Diniz
1Núcleo de Espectroscopia e Estrutura Molecular (NEEM), Department of Chemistry - Federal University of Juiz de Fora - Minas Gerais, 36036-900, Brazil.
Abstract:
The metal site in the title compound [MnCl(2)(C(12)H(12)N(2))(2)]·2.5H(2)O has a distorted octa-hedral geometry, coordinated by four N atoms of two 5,5'-dimethyl-2,2'-dipyridine ligands and two Cl atoms. Two and a half water molecules of hydration per complex unit are observed in the crystal structure. The compounds extend along the c axis with O-H⋯Cl, O-H⋯O, C-H⋯Cl and C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.70 (2) Å] contributing substanti-ally to the crystal packing. The Mn and one of the water O atoms, the latter being half-occupied, are located on special positions, in this case a rotation axis of order 2.
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