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Updated: May 30, 2026

Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry
Published on: June 8, 2022
Poly[aqua-bis-[μ(2)-2-(pyridin-4-ylsulfan-yl)acetato]-zinc]
Zhi-Chao Wang1, Bo Ding, Xiu-Guang Wang
1College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, People's Republic of China.
Abstract:
The crystal structure of the title complex, [Zn(C(7)H(6)NO(2)S)(2)(H(2)O)](n), consists of extended layers parallel to (001) with 2-(pyridin-4-ylsulfan-yl)acetate ligands bridging the Zn(II) atoms. The Zn(II) atom shows a distorted penta-gonal-bipyramidal coordination environment. The Zn(II) and one O atom are situated on a crystallographic twofold rotation axis. In the crystal, intra-layer O-H⋯O hydrogen-bond inter-actions help to consolidate the coordination layer.

