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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
2-Hydrazinyl-4-methyl-1,3-benzothia-zole
Acta Crystallographica. Section E, Structure Reports Online
|August 13, 2011
Summary
This study details the crystal structure of a novel sulfur-containing compound, C(8)H(9)N(3)S. Molecular analysis reveals near-planar geometry with specific hydrogen bonding in its crystalline form.
Area of Science:
- Crystallography
- Chemical structure analysis
Background:
- Understanding the three-dimensional arrangement of atoms in molecules is crucial for predicting chemical properties.
- The study of novel organic compounds contributes to the broader field of materials science.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(8)H(9)N(3)S.
- To analyze the molecular geometry and intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of atomic coordinates and bond lengths/angles provided geometric insights.
Main Results:
- The title compound, C(8)H(9)N(3)S, exhibits a near-planar molecular structure.
- A notable deviation was observed in the terminal -NH(2) group.
- Intermolecular N-H⋯N hydrogen bonds were identified, leading to the formation of (001) sheets in the crystal.
Conclusions:
- The crystal packing of C(8)H(9)N(3)S is governed by specific hydrogen bonding patterns.
- The determined structure provides a foundation for further investigations into the compound's physical and chemical properties.
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