Tetra-methyl 5,5'-[4,5-dicyano-1,2-phenyl-enebis(-oxy)]diisophthalate chloro-form monosolvate
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Updated: May 30, 2026

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Abstract:
In the title compound, C(28)H(20)N(2)O(10)·CHCl(3), the phen-oxy rings are inclined to the central phenyl ring at dihedral angles of 84.71 (13) and 80.56 (13)°. In the crystal, pairs of weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules related by an inversion center, forming dimers. There are also C-H⋯π inter-actions present.
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Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...