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Updated: May 30, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Palladium induced macrocyclic preorganization for stabilization of a tetrathiafulvalene mixed-valence dimer
Christopher Bejger1, Christina M Davis, Jung Su Park
1Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712, USA.
Abstract:
Ditopic metalation of a flexible "Pacman"-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.
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