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Related Experiment Video

Updated: May 30, 2026

Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis
13:09

Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis

Published on: January 6, 2016

pH sensing using boron doped diamond electrodes.

Stéphane Fierro1, Naoko Mitani, Christos Comninellis

  • 1Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi, Yokohama, Japan.

Physical Chemistry Chemical Physics : PCCP
|August 23, 2011
PubMed
Summary

Boron-doped diamond (BDD) electrodes offer a stable, accurate alternative to traditional pH sensors. This new method leverages a pH-dependent reaction on BDD, unaffected by common solution interferences.

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Area of Science:

  • Electrochemistry
  • Materials Science
  • Analytical Chemistry

Background:

  • Conventional glass pH electrodes suffer from instability and interference.
  • Development of novel electrode materials is crucial for advanced sensing applications.
  • Boron-doped diamond (BDD) exhibits unique electrochemical properties.

Purpose of the Study:

  • To evaluate Boron-doped diamond (BDD) electrodes as next-generation pH sensors.
  • To demonstrate a novel pH sensing method based on potential changes.
  • To assess the stability and accuracy of BDD electrodes in real-world samples.

Main Methods:

  • Utilized a chronopotentiometric method measuring potential changes related to the hydrogen evolution reaction.
  • Investigated the pH-dependent potential shift.

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All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
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Published on: January 19, 2018

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Last Updated: May 30, 2026

Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis
13:09

Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis

Published on: January 6, 2016

All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
11:33

All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics

Published on: January 19, 2018

  • Tested the influence of alkali cations and electrochemically active compounds.
  • Employed BDD electrodes characterized by a wide potential window and low background current.
  • Main Results:

    • BDD electrodes demonstrated high stability and accuracy in pH measurements.
    • The developed method showed no interference from alkali cations.
    • Adjusting current density effectively minimized interference from active compounds.
    • Accurate pH measurements were achieved even in complex samples like tap water.

    Conclusions:

    • BDD electrodes are highly suitable for developing stable, accurate, and glass-free pH sensors.
    • The proposed chronopotentiometric method offers significant advantages over conventional pH sensing techniques.
    • BDD-based sensors represent a promising advancement in electrochemical sensing technology.