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Characterization of ethyl cellulose polymer.
Tazin Mahnaj1, Salah U Ahmed, Fotios M Plakogiannis
1Division of Pharmaceutical Sciences, Arnold and Marie Schwartz College of Pharmacy and Health Sciences, Long Island University, Brooklyn, New York , USA. tmahnaj@aol.com
This study characterized ethyl cellulose (EC) polymer properties, finding a 7% ethanol solution optimal for film preparation. The research aimed to understand EC behavior before plasticizer interactions, avoiding pre-additive commercial dispersions.
Area of Science:
- Polymer Science
- Materials Science
Background:
- Ethyl cellulose (EC) is a widely used polymer, but its properties can be affected by additives in commercial dispersions.
- Understanding the intrinsic properties of EC polymer is crucial before incorporating plasticizers for specific applications.
Purpose of the Study:
- To characterize the fundamental properties of Ethocel Std.10 FP Premium ethyl cellulose polymer.
- To establish optimal conditions for preparing EC films.
- To evaluate the mechanical and thermal behavior of EC films without plasticizers.
Main Methods:
- Solubility, morphology, and thermal properties of EC polymer were analyzed.
- Viscosity of EC solutions in ethanol was determined to find optimal film-forming concentrations.
- X-ray diffraction and dynamic mechanical analysis were used to assess film structure and flexibility.
Main Results:
- A 7% EC solution in ethanol was identified as optimal for film preparation.
- EC polymer and EC films exhibited similar thermal behavior but differed in crystallite and amorphous region arrangements.
- Unplasticized EC films demonstrated poor flexibility and low elongation.
Conclusions:
- Ethocel EC polymer powder can be characterized in-house to understand its intrinsic properties.
- The study provides a baseline for investigating plasticizer interactions with pure EC.
- This approach avoids the confounding effects of additives present in commercial EC dispersions.
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