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Updated: May 30, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Dynamic behaviour of Ru and Ru-Pt complexes containing tetrahedro-P4 ligand
Vincenzo Mirabello1, Maria Caporali, Vito Gallo
1Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici, Sesto Fiorentino, Firenze, Italy.
Abstract:
Dynamic processes involving the P(4) cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)(2)(H)(η(1)-P(4))]BF(4) and for the bimetallic derivative trans-[Ru(dppm)(2)(H)(μ ,η(1:2)-P(4)){Pt(PPh(3))(2)}]BF(4) as demonstrated by NMR experiments and DFT calculations.
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