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Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
Published on: September 5, 2018
Molecular doping of porous organic cages
Tom Hasell1, Marc Schmidtmann, Andrew I Cooper
1Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Liverpool, UK.
Abstract:
Porous organic cages can act as hosts for the three-dimensional alignment of guests such as halogens and organometallics. Porous single crystals are doped by vapor sublimation to produce diamondoid arrangements of guests such as I(5)(-) and OsO(4), leading to marked conductivity enhancement in the case of I(5)(-).
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