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Updated: May 29, 2026

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Transformation of carbon dioxide with homogeneous transition-metal catalysts: a molecular solution to a global
Mirza Cokoja1, Christian Bruckmeier, Bernhard Rieger
1Chair of Inorganic Chemistry, Molecular Catalysis Catalysis Research Center, Technische Universität München, Ernst-Otto-Fischer Strasse 1, 85747 Garching, Germany.
Abstract:
A plethora of methods have been developed over the years so that carbon dioxide can be used as a reactant in organic synthesis. Given the abundance of this compound, its utilization in synthetic chemistry, particularly on an industrial scale, is still at a rather low level. In the last 35 years, considerable research has been performed to find catalytic routes to transform CO(2) into carboxylic acids, esters, lactones, and polymers in an economic way. This Review presents an overview of the available homogeneous catalytic routes that use carbon dioxide as a C(1) carbon source for the synthesis of industrial products as well as fine chemicals.
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