Spherical silica micro/nanomaterials with hierarchical structures: synthesis and applications
1Functional Nanomaterials Laboratory and Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry (TIPC), Chinese Academy of Sciences, Zhongguancundonglu 29, Haidianqu, Beijing 100190, China.
Abstract:
This paper reviews the progress made recently in synthesis and applications of spherical silica micro/nanomaterials with multilevel (hierarchical) structures. The spherical silica micro/nanomaterials with hierarchical structures are classified into four main structural categories that include (1) hollow mesoporous spheres, (2) core-in-(hollow porous shell) spheres, (3) hollow spheres with multiple porous shells and (4) hierarchically porous spheres. Due to the complex structures and being focused on spherical silica micro/nanomaterials, some novel methods based on the combination of two routine methods or two surfactants, and some special synthetic strategies are proposed to produce the spherical silica micro/nanomaterials with hierarchical structures. Compared with the same-sized solid, porous or hollow silica spheres, these fantastic spherical silica micro/nanomaterials with hierarchical structures exhibit enhanced properties which may enable them to be used in broad and promising applications as ideal scaffolds (carriers) for biological, medical, and catalytic applications.
