Wavelength-dependent emission enhancement through the design of active plasmonic nanoantennas

Owing to the competition between the radiative and non-radiative decay channels occurring in plasmonic assemblies, we show here how to conceive a long pass emission filter and actually design it. We report the synthesis of gold@silica nanoparticles grafted with dye molecules. The control of the thickness of the silica shell allows us to tune the distance between the metal core and the dye molecules. Assemblies of small number (1 to 7) of these core-shell (CS) particles, considered as multimers, have also been produced for the first time. We show that the shaping of the emission spectra of the multimers is drastically enhanced by comparison with the corresponding monomers. We also show a strong enhancement of the decay rates at the LSP resonance, dominated by the non-radiative energy tranfer from the active medium to the metal. The decay rates decrease as the detuning between the long wavelength emission and the LSP resonance increases.