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Updated: May 29, 2026

A Guide to Concentration Alternating Frequency Response Analysis of Fuel Cells
Published on: December 11, 2019
Spontaneous oscillations of cell voltage, power density, and anode exit CO concentration in a PEM fuel cell
Hui Lu1, Liisa Rihko-Struckmann, Kai Sundmacher
1Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstrasse 1, D-39106 Magdeburg, Germany. huilu@dicp.ac.cn
Abstract:
The spontaneous oscillations of the cell voltage and output power density of a PEMFC (with PtRu/C anode) using CO-containing H(2) streams as anodic fuels have been observed during galvanostatic operating. It is ascribed to the dynamic coupling of the CO adsorption (poisoning) and the electrochemical CO oxidation (reactivating) processes in the anode chamber of the single PEMFC. Accompanying the cell voltage and power density oscillations, the discrete CO concentration oscillations at the anode outlet of the PEMFC were also detected, which directly confirms the electrochemical CO oxidation taking place in the anode chamber during galvanostatic operating.
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