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Related Concept Videos

Atomic Nuclei: Nuclear Relaxation Processes01:23

Atomic Nuclei: Nuclear Relaxation Processes

In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis,  the precessing magnetic moments are randomly oriented around the z-axis. This...
Atomic Nuclei: Magnetic Resonance01:05

Atomic Nuclei: Magnetic Resonance

The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external magnetic field, as the spins precess at the Larmor frequency, the excess population results in a net magnetization oriented along the z axis. When a pulse or a short burst of radio waves at the Larmor frequency is applied along the x axis, the coupling of frequencies causes resonance and flips the nuclear spins of the excess population from the...
Atomic Nuclei: Nuclear Magnetic Moment00:59

Atomic Nuclei: Nuclear Magnetic Moment

All atomic nuclei are positively charged. When they have a nonzero spin, they behave like rotating charges. As a consequence of their charge and spin, these nuclei generate a magnetic field (B). This, in turn, gives rise to a magnetic moment (μ), which is randomly oriented in the absence of an external magnetic field. When an external magnetic field (B0) is applied, the magnetic moment vectors can align with the field or against it in 2 + 1 orientations. A hydrogen nucleus, which is just a...
Atomic Nuclei: Nuclear Spin State Overview01:03

Atomic Nuclei: Nuclear Spin State Overview

NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of one, the...
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Magnetic Fields

A moving charge or a current creates a magnetic field in the surrounding space, in addition to its electric field. The magnetic field exerts a force on any other moving charge or current that is present in the field. Like an electric field, the magnetic field is also a vector field. At any position, the direction of the magnetic field is defined as the direction in which the north pole of a compass needle points.
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Potential Due to a Magnetized Object

Magnetic dipoles in magnetic materials are aligned when placed under an external magnetic field. For paramagnets and ferromagnets, dipole alignment occurs in the direction of the magnetic field. However, the dipoles align opposite to the field in the case of diamagnets. This state of magnetic polarization due to the external field is called magnetization. Magnetization is defined as the dipole moment per unit volume. It plays a similar role to polarization in electrostatics.
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Optimizing Magnetic Force Microscopy Resolution and Sensitivity to Visualize Nanoscale Magnetic Domains
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Optimizing Magnetic Force Microscopy Resolution and Sensitivity to Visualize Nanoscale Magnetic Domains

Published on: July 20, 2022

Uniform excitations in magnetic nanoparticles.

Steen Mørup1, Cathrine Frandsen, Mikkel Fougt Hansen

  • 1Department of Physics, Building 307, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.

Beilstein Journal of Nanotechnology
|October 7, 2011
PubMed
Summary

Magnetic nanoparticles below blocking temperature exhibit uniform excitations, causing linear temperature dependence for magnetization and hyperfine fields, unlike bulk materials. This behavior is studied using Mössbauer spectroscopy and inelastic neutron scattering.

Keywords:
Mössbauer spectroscopycollective magnetic excitationsneutron scatteringspin wavessuperparamagnetic relaxation

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Nanotechnology

Background:

  • Superparamagnetic nanoparticles exhibit unique magnetic dynamics below their blocking temperature.
  • Bulk magnetic materials follow the Bloch T(3/2) law for temperature dependence.

Purpose of the Study:

  • To review magnetic excitations in nanoparticles below the superparamagnetic blocking temperature.
  • To contrast nanoparticle magnetic behavior with bulk materials.

Main Methods:

  • Mössbauer spectroscopy to study temperature dependence of average magnetization.
  • Inelastic neutron scattering to investigate the energy of uniform excitations.

Main Results:

  • Magnetic dynamics in nanoparticles below blocking temperature are dominated by uniform excitations.
  • A linear temperature dependence of magnetization and magnetic hyperfine field is observed.
  • This contrasts with the Bloch T(3/2) law typically seen in bulk magnetic materials.

Conclusions:

  • Uniform excitations are key to understanding nanoparticle magnetism below blocking temperature.
  • Mössbauer spectroscopy and inelastic neutron scattering are effective tools for studying these phenomena.